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New Aspects of Zirconium Containing Organic Compounds
 
 
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New Aspects of Zirconium Containing Organic Compounds [Hardcover]

Ilan Marek (Editor)

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Book Description

3540222219 978-3540222217 November 2, 2005 1
Metal carbene complexes have made their way from organometallic curiosities to valuable reagents and catalysts. They offer novel synthetic opportunities in carbon-carbon bond formation based on either carbene-centered reactions or on metal-templated processes which makes them indispensable in modern synthetic methodology. The most prominent metal carbenes are now either commercially available or easy to synthesize and handle with modern laboratory techniques. This volume organized in eight chapters written by the leading scientists in the field illustrates the theoretical background, non-classical nucleophilic and cycloaddition patterns, chromium-templated benzannulation and photo-induced reactions, rhodium-catalyzed carbene transfer as well as the principles and applications of olefin metathesis which has coined the progress in synthetic methodology over the past decade. Designed for researchers in academia and industry as well as graduate students it presents the state-of-the-art potential of carbene complexes in modern organic synthesis.

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From the reviews: "This small volume is packed with valuable information. … The virtue of this book lies in its voluminous data and complete referencing of the various topics presented. As such, it will be a useful source for researchers focused on particular targeted areas." (Jeffrey Schwartz, Journal of the American Chemical Society, Vol. 128 (21), 2006)

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Inside This Book (learn more)
Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
benzamidinate complexes, dienyl zirconocenes, benzamidinate ligands, hydrozirconation reaction, enantiomer interconversion, elastomeric polypropylene, zirconocene complexes, unique isomer, zirconocene derivatives, methane elimination, catalytic precursors, vinylic position, zirconium complexes, stereoselective preparation, diastereomer ratio, isotactic polymer, propylene polymerization, elastomeric polymer, allylic amines, allylic ethers, ethylene carbonate, atactic polypropylene, atactic polymer, two deuteriums, allyl complexes
Key Phrases - Capitalized Phrases (CAPs): (learn more)
Tetrahedron Lett, Organomet Chem, Chem Rev, Org Chem, Chem Soc Dalton Trans, Chem Soc Chem Commun, Angew Chem Int Ed Engl, New York, Product Yield, Chem Lett, Mol Catal, Acc Chem Res, Chem Ber, Springer-Verlag Berlin Heidelberg, Bull Acad Sci, Div Chem Sci
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