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Atom Resolved Surface Reactions: Nanocatalysis (RSC Nanoscience and Nanotechnology Series) (RSC Nanoscience & Nanotechnology)
 
 
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Atom Resolved Surface Reactions: Nanocatalysis (RSC Nanoscience and Nanotechnology Series) (RSC Nanoscience & Nanotechnology) [Hardcover]

P R Davies (Author), M W Roberts (Author), Paul O'Brien (Series Editor), Harry Kroto (Series Editor), Harold Craighead (Series Editor)

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Book Description

0854042695 978-0854042692 December 21, 2007 1

This book offers a unique perspective of the impact of scanning probe microscopies on our understanding of the chemistry of the surface at the nanoscale.

Research oriented, with the concepts gleaned from Scanning Tunneling Microscopy being related to the more established and accepted views in surface chemistry and catalysis the authors have addresses the question How do the models based on classical spectroscopic and kinetic studies stand up to scrutiny at the atom - resolved level? In taking this approach the reader, new to the field of surface chemistry, should be able to obtain a perspective on how the evidence from STM confirms or questions long standing tenets. An emphasis is given to how did we get to where we are now and a large number of figures from the literature are included along with suggestions for further reading. This book will appeal to all those who wish to become familiar with the contribution Scanning Tunneling Microscopy has made to the understanding of the field of surface chemistry and heterogeneous catalysis and also to those who are new to catalysis, a fascinating and important area of chemistry.


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Editorial Reviews

Review

Through a scanner darkly

Atom resolved surface reactions: nanocatalysis

P. R. Davies and M. W. Roberts

Cambridge, UK: RSC Publishing 2008 | 221pp | (HB) ISBN 9780854042692

 

Reviewed by Stephen J Jenkins

The advent of scanning tunnelling microscopy (STM) in the 1980s promised to revolutionise studies of the adsorption, diffusion, reaction and desorption processes that define the ground-rules of heterogeneous catalysis. It soon became clear, however, that proper interpretation of beguiling STM images was a subtle skill, requiring careful cross-reference with theory and other more established techniques. This welcome book reviews the remarkable progress that has nevertheless been made via STM in understanding surface catalysis at an atomically-resolved level. Beginning with an engagingly personal historical overview of early surface studies, and proceeding via two chapters on the fundamentals of experimental surface science and of STM itself, the balance of the book is devoted to a survey of notable applications abstracted from the recent literature. Topics range from the traditional (catalytic oxidation; alkali metal, sulfur and thiol adsorption) to the fashionable (high-pressure STM; nanoparticle reactivity; surface engineering) and give a good flavour of the technique's current ubiquity.

Chemistry World, 2008, 5(8), p. 72

Book Description

This book offers a unique perspective of the impact of scanning probe microscopies on our understanding of the chemistry of the surface at the nanoscale. Topics discussed include: the dynamics of oxygen chemisorption at metal surfaces; control of oxygen states and surface reconstruction; dissociative chemisorption of diatomic and hydrocarbon molecules; nanoparticles and chemical reactivity; STM at high pressures; and structural studies of sulfur containing molecules. Ideal for those who wish to become familiar with the contribution STM has made to the understanding of the field of surface chemistry and heterogeneous catalysis and also to those who are new to catalysis.

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Inside This Book (learn more)
Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
surface modification, atom resolved level, oxygen state present, sulfur adlayer, brim sites, imide species, sulfur adatoms, oxygen adatoms, nitrogen adatoms, oxygen adlayer, coadsorption studies, dioxygen bond cleavage, oxygen transients, missing row structure, oxygen islands, oxygen chemisorption, oxygen states, bimetallic surfaces, tunnelling conditions, sulfur adsorption, sulfur coverages, resolved evidence, dissociative chemisorption, catalytic oxidation reactions, oxygen coverage
Key Phrases - Capitalized Phrases (CAPs): (learn more)
New York, Further Reading, Faraday Trans, Surf Sei, Atom Resolved Evidence, Scanning Tunnelling Microscopy, Surface Science Relevant, Fritz Haber Institute, Faraday Soc, Faraday Discuss, High Pressure, Surf Sci, Monte Carlo, Surface Engineering, Kluwer Academic, Some Milestones, Plenum Press, International Congress, The Chemical Physics of Solid Surfaces, Academic Press, General Electric, Clarendon Press, Chemistry of the Metal-Gas Interface, American Chemical Society, Faraday Symposium
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