Metal carbene complexes have made their way from organometallic curiosities to valuable reagents and catalysts. They offer novel synthetic opportunities in carbon carbon bond formation based on either carbene-centered reactions or on metal-templated processes which makes them indispensable in modern synthetic methodology. The most prominent metal carbenes are now either commercially available or easy to synthesize and handle by modern laboratory techniques. This volume organized in eight chapters written by the leading scientists in the field illustrates the theoretical background, non-classical nucleophilic and cycloaddition patterns, chromium-templated benzannulation and photo-induced reactions, rhodium-catalyzed carbene transfer as well as the principles and applications of olefin metathesis which coined the progress in synthetic methodology over the past decade. Designed for researchers in academia and industry as well as graduate students it presents the state-of-the-art potential of carbene complexes in modern organic synthesis.
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From the reviews: "As stated by the editor, ‘the aim of this book is to convince the reader that metal carbene complexes have made their way from … for application in synthesis and catalysis.’ By this measure, this book has succeeded. … this is a valuable book for those who are interested in research in the area of carbene complexes in organic synthesis. … The contributions are up-to-date, and they have references … . The book is highly recommended … ." (William D. Wulff, Journal of the American Chemical Society, Vol. 127 (45), 2005)
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alkenylcarbene complexes, alkynylcarbene complexes, benzannulation reaction, ruthenium precatalysts, metathesis substrate, diastereoselective benzannulation, alkoxycarbene complexes, metal carbene reactions, benzannulation product, metathesis precursor, imine carbenes, diyne metathesis, chromium alkoxycarbenes, aminocarbene complexes, carbene carbon atom, enyne metathesis, cross metathesis, self metathesis, chiral dirhodium, cyclopentene derivatives, metathesis catalysts, ruthenium carbene complexes, alkyne metathesis, carbene ligand, intermolecular cyclopropanation Key Phrases - Capitalized Phrases (CAPs): (learn more)
Org Chem, Tetrahedron Lett, Organomet Chem, Org Lett, Chem Ber, Chem Commun, Angew Chem Int Ed Engl, Chem Eur, Chem Rev, New York, Acc Chem Res, Adv Synth Catal, Springer-Verlag Berlin Heidelberg, Chem Soc Perkin Trans, Chromium-Templated Benzannulation Reactions, Phys Chem, Pure Appl Chem, Carbene Product, Chem Fur, Chem Soc Dalton Trans, Complex Ref, Hely Chim Acta, Photoinduced Reactions of Metal Carbenes, Hegedus Table, Mol Catal New!
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alkenylcarbene complexes, alkynylcarbene complexes, benzannulation reaction, ruthenium precatalysts, metathesis substrate, diastereoselective benzannulation, alkoxycarbene complexes, metal carbene reactions, benzannulation product, metathesis precursor, imine carbenes, diyne metathesis, chromium alkoxycarbenes, aminocarbene complexes, carbene carbon atom, enyne metathesis, cross metathesis, self metathesis, chiral dirhodium, cyclopentene derivatives, metathesis catalysts, ruthenium carbene complexes, alkyne metathesis, carbene ligand, intermolecular cyclopropanation Key Phrases - Capitalized Phrases (CAPs): (learn more)
Org Chem, Tetrahedron Lett, Organomet Chem, Org Lett, Chem Ber, Chem Commun, Angew Chem Int Ed Engl, Chem Eur, Chem Rev, New York, Acc Chem Res, Adv Synth Catal, Springer-Verlag Berlin Heidelberg, Chem Soc Perkin Trans, Chromium-Templated Benzannulation Reactions, Phys Chem, Pure Appl Chem, Carbene Product, Chem Fur, Chem Soc Dalton Trans, Complex Ref, Hely Chim Acta, Photoinduced Reactions of Metal Carbenes, Hegedus Table, Mol Catal New!
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Front Cover | Table of Contents | First Pages | Index | Back Cover | Surprise Me!
Citations (learn more)
This book cites 8
books:
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- Organolithiums in Enantioselective Synthesis (Topics in Organometallic Chemistry) by David M. Hodgson in Front Matter
- Lanthanides: Chemistry and Use in Organic Synthesis (Topics in Organometallic Chemistry) (v. 2) by Shu Kobayashi in Front Matter
- New Aspects of Zirconium Containing Organic Compounds by Ilan Marek in Front Matter
- Theoretical Aspects of Transition Metal Catalysis (Topics in Organometallic Chemistry) by Gernot Frenking in Front Matter
- Activation of Unreactive Bonds and Organic Synthesis (Topics in Organometallic Chemistry) by Shinji Murai in Front Matter
See all 8 books this book cites
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