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Catenanes, Rotaxanes, and Knots [Hardcover]

J. P. Sauvage (Editor), Christiane Dietrich-Buchecker (Editor)


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Book Description

April 9, 1999 3527295720 978-3527295722 1
This journey through the fascinating world of molecular topology focuses on catenanes, rotaxanes and knots, their synthesis, properties, and applications and the theory of interlocking and interpenetrating molecules. Nearly one hundred years of progress have passed since Willstätter's speculative vision of a molecule consisting of two interlinked rings. But even today the synthesis of such structures are a challenge to the creativity of synthetic chemists. These molecules are not only of academic interest, since they occur naturally. In such molecules as DNA, knots and related topological features play a key role in biochemical processes. In addition, extensive research on the properties of polyrotaxanes and polycatenanes show potential applications as molecular magnets, wires or switches.

Twelve international leading experts in the field present the broad and impressive spectrum of the topology of these molecules, from theoretical aspects and new pathways in synthesis to probing their properties. All researchers working in this interdisciplinary area, whether organic, inorganic or polymer chemists, as well as material scientists, will welcome this comprehensive and up-to-date work as an inspiring source for creative research ideas.

Editorial Reviews

From the Back Cover

Molecular Catenanes, Rotaxanes and Knots A Journey Through the World of Molecular Topology J.-P. Sauvage, C. Dietrich-Buchecker (Eds.) This journey through the fascinating world of molecular topology focuses on catenanes, rotaxanes and knots, their synthesis, properties, and applications and the theory of interlocking and interpenetrating molecules. Nearly one hundred years of progress have passed since Willstätter’s speculative vision of a molecule consisting of two interlinked rings. But still today the synthesis of such structures are a challenge to the creativity of synthetic chemists. These molecules are certainly not only of academic interest, as they exist in nature. In molecules like DNA, knots and related topological features play a key role in biochemical processes. In addition, extensive research on the properties of polyrotaxanes and polycatenanes show potential applications as molecular magnets, wires or switches. Twelve international leading experts in this field give a broad and impressive spectrum of the topology of these molecules, from theoretical aspects and new pathways in synthesis to the probing of their properties. All researchers working in this interdisciplinary field, organic, inorganic or polymer chemists, as well as material scientists, will welcome this comprehensive and state-of-the -art work as an inspiring source for creative research ideas.

Product Details

  • Hardcover: 416 pages
  • Publisher: Wiley-VCH; 1 edition (April 9, 1999)
  • Language: English
  • ISBN-10: 3527295720
  • ISBN-13: 978-3527295722
  • Product Dimensions: 9.5 x 7 x 0.9 inches
  • Shipping Weight: 1.9 pounds
  • Amazon Best Sellers Rank: #4,706,504 in Books (See Top 100 in Books)

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Inside This Book (learn more)
First Sentence:
Chemical topology was undoubtedly discussed for decades before serious laboratory efforts began. Read the first page
Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
catenane units, threaded crown ether, catenane monomers, image cell complex, parallel interpenetration, polyhedral catenanes, ester rotaxane, polymeric catenanes, topological bonds, unit tangle, triple layered cyclophane, topological protection, cyclic polystyrene, ether rotaxane, inclined interpenetration, rotaxane units, attaching vertices, threading efficiency, topological chirality, catenane formation, cyclic strands, molecular trefoil knot, rotaxane synthesis, slipping approach, reporter strand
Key Phrases - Capitalized Phrases (CAPs): (learn more)
New York, American Chemical Society, Tetrahedron Lett, Pure Appl, Academic Press, Liebigs Ann, Materials Research Society, Universität Bonn, Large Ring Molecules, State University, Virginia Polytechnic Institute, Englewood Cliffs, High-Yield Template Syntheses, John Wiley, Kauffman's Theorem, Liehigs Ann, Perkin Trans, Prentice Hall, Rapid Commun, Rubber Chem, Angew Chem, Concluding Comments, Cornell University Press, Kuratowski's Theorem, Pergamon Press
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