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Dynamic Spin Chemistry: Magnetic Controls and Spin Dynamics of Chemical Reactions
 
 
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Dynamic Spin Chemistry: Magnetic Controls and Spin Dynamics of Chemical Reactions [Hardcover]

Saburo Nagakura (Editor), Hisahary Hayashi (Editor), Tohru Azumi (Editor)

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Book Description

January 14, 1999 0471328367 978-0471328360 1
Dynamic Spin Chemistry Edited by Saburo Nagakura, Hisaharu Hayashi and Tohru Azumi Because of increasing concerns over the effects of electromagnetic radiation on the human body, it has become essential to understand how chemical and biological reactions are affected by magnetic fields. Dynamic Spin Chemistry focuses on theoretical and experimental research showing the great influence on the dynamic behavior of molecules due to external magnetic fields, such as magnetic quenching of gaseous fluorescence, effects on chemical reaction rates and chemically induced dynamic nuclear and electron polarization. This book discusses both the theoretical and experimental foundations of dynamic spin chemistry, as well as its future trends. After the introductory chapter, the next three chapters discuss magnetic field effects and magnetic isotope effects on chemical reactions in solution and on the dynamic behavior of excited molecules in the gas phase. Subsequent chapters deal with the effects on chemical equilibria under large fields; spin spectroscopy; chemically induced dynamic electron polarization (CIDEP) studies and reaction yield-detected ESR. This book will be of interest to researchers and graduate students in pure and applied chemistry, physics or biology having an interest in photochemistry, photophysics or photobiology.

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From the Back Cover

Dynamic Spin Chemistry Edited by Saburo Nagakura, Hisaharu Hayashi and Tohru Azumi Because of increasing concerns over the effects of electromagnetic radiation on the human body, it has become essential to understand how chemical and biological reactions are affected by magnetic fields. Dynamic Spin Chemistry focuses on theoretical and experimental research showing the great influence on the dynamic behavior of molecules due to external magnetic fields, such as magnetic quenching of gaseous fluorescence, effects on chemical reaction rates and chemically induced dynamic nuclear and electron polarization. This book discusses both the theoretical and experimental foundations of dynamic spin chemistry, as well as its future trends. After the introductory chapter, the next three chapters discuss magnetic field effects and magnetic isotope effects on chemical reactions in solution and on the dynamic behavior of excited molecules in the gas phase. Subsequent chapters deal with the effects on chemical equilibria under large fields; spin spectroscopy; chemically induced dynamic electron polarization (CIDEP) studies and reaction yield-detected ESR. This book will be of interest to researchers and graduate students in pure and applied chemistry, physics or biology having an interest in photochemistry, photophysics or photobiology.

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Inside This Book (learn more)
First Sentence:
It is obvious that electrons within atoms and molecules play an essential role in chemical reactions. Read the first page
Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
increasing excess vibrational energy, dynamic spin chemistry, emissive polarization, pyrimidine vapor, acetone ketyl, azaaromatic molecules, magnetochemical potential, predissociation threshold, rotational state dependence, small molecule limit, triplet state coupled, absorptive polarization, increasing excess energy, magnetic fluorescence, banded fluorescence, permittivity dependence, room temperature upon excitation, magnetic isotope effects, nuclear spin polarization, radical pair model, biradical lifetimes, interradical distance, squalane solution, cage product, hfc mechanism
Key Phrases - Capitalized Phrases (CAPs): (learn more)
Chem Phys, Molecular Magnetism, New York, Phys Chem, Phys Lett, Boca Raton, Chem Soc, Reaction-Yield-Detected Magnetic Resonance, Magn Reson, Optically Detected Magnetic Resonance, Plenum Press
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