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Electron Paramagnetic Resonance: Elementary Theory and Practical Applications [Hardcover]

John A. Weil (Author), James R. Bolton (Author), John E. Wertz (Author)
4.0 out of 5 stars  See all reviews (2 customer reviews)


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Hardcover, March 14, 1994 --  
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Electron Paramagnetic Resonance: Elementary Theory and Practical Applications Electron Paramagnetic Resonance: Elementary Theory and Practical Applications 4.0 out of 5 stars (2)
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Book Description

0471572349 978-0471572343 March 14, 1994 1
Focusing primarily on isolated paramagnetic species, Electron Paramagnetic Resonance is designed to provide senior undergraduate and graduate students as well as professionals with the essential understanding needed to use this technique and be active in various specialized fields of interest.

Electron Paramagnetic Resonance enables those with no previous background in quantum mechanics to gain a fundamental grasp of EPR. It helps those with moderate training to acquire more sophisticated mathematical and quantum-mechanical skills and a knowledge of powerful theoretical and experimental techniques—tools that will allow them to interpret a wide range of EPR spectra.

This important work also introduces many exciting new EPR developments in progress, including time-resolved spectroscopy, which involves the acquisition of EPR data for short-lived species. In addition, it highlights the increasing complexity of the experimental equipment currently used, including spectrometers that operate both in the classical continuous-wave mode and in pulsed mode. This book also discusses how computers can direct spectrometer control and data acquisition, analyze data to yield to underlying parameters, and produce accurate simulated spectra.

Readers will acquire a heightened historical appreciation of the EPR technique, discovering how EPR studies have:

  • confirmed the existence of triplet states, establishing that new adsorption bands observed in optical spectra following excitation by light of certain molecules arise from the unpairing of electron spins
  • identified chlorophyll radicals as the primary donor in the photosynthesis process, as well as other key intermediates in this reaction
  • clarified the structure and function of systems of biomedical interest, including oxygen carriers and various enzymes
  • uncovered paramagnetic species in insulators and semiconductors and described their environment
  • facilitated chemists' investigation of reaction mechanisms

Complete with problem sets and concise bibliographies at the end of each chapter, as well as tutorial mathematical and quantum-mechanical appendices, this book is must reading for aspiring scientists in the field of physical chemistry and spectroscopy.

Using this book, you will be able to gain a fundamental grasp of EPR—even if you have no previous background in quantum mechanics. This important work also helps those with some training to acquire more sophisticated mathematical and quantum-mechanical skills and a knowledge of powerful theoretical and experimental techniques—tools that will allow them to interpret a wide range of EPR spectra.

You'll find out about many exciting new EPR developments in progress, including time-resolved spectroscopy, which involves the acquisition of EPR data for short-lived species. This book also discusses computers that direct spectrometer control and data acquisition, analyze data to yield to underlying parameters and produce accurate simulated spectra.

Complete with problem sets and concise bibliographies at the end of each chapter, this book is must reading for aspiring scientists in the field of physical chemistry and spectroscopy.


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Editorial Reviews

Review

"Highly recommended to researchers seeking applications that would harness the potential of EPR spectroscopy to related fields of study. The authors are to be congratulated on producing a truly formidable EPR bible that lays claim once again to being the standard of work on the subject." (Journal of Chemical Education, January 2009) --This text refers to an alternate Hardcover edition.

From the Publisher

An introduction to and a tutorial on electron paramagnetic resonance (EPR) spectroscopy. Considers the use of EPR techniques to solve problems of interest in organic, inorganic, biological or analytical chemistry, chemical physics, mineralogy and geophysics. Demonstrates the similarities and unity of approach possible for all the myriad of paramagnetic systems open to study by EPR. Features problems sets of varying degrees of difficulty.

Product Details

  • Hardcover: 592 pages
  • Publisher: Wiley-Interscience; 1 edition (March 14, 1994)
  • Language: English
  • ISBN-10: 0471572349
  • ISBN-13: 978-0471572343
  • Product Dimensions: 9.5 x 6.4 x 1.3 inches
  • Shipping Weight: 2.1 pounds
  • Average Customer Review: 4.0 out of 5 stars  See all reviews (2 customer reviews)
  • Amazon Best Sellers Rank: #2,298,805 in Books (See Top 100 in Books)

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4 of 4 people found the following review helpful:
5.0 out of 5 stars Clear and comprehensive introduction, October 17, 2007
By 
E. Olmon (Pasadena, CA USA) - See all my reviews
(REAL NAME)   
As a graduate student at Caltech, I first started learning about EPR from the first edition of this book. The first edition (much slimmer) was not perfect, and I found useful complementary information in the works of Poole and Baird, but I noticed that I kept returning to Weil and Bolton for answers to my most fundamental questions. The appendices including lucid treatments on instrumental design and the relevant quantum mechanics were particularly useful in my overall understanding of the theory and practice of EPR. In the newest edition, the subject is given an even broader overview, with clear discussions of modern techniques. The best of the bunch. I also recommend Poole's _Electron Spin Resonance: A Comprehensive Treatise on Experimental Techniques_, Bersohn Baird's _Electron Paramagnetic Resonance_, and the _Handbook of Electron Spin Resonance_, edited by Poole and Farach.
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6 of 7 people found the following review helpful:
3.0 out of 5 stars comprehensive, but poorly written, January 27, 2000
By 
+++ (OR, United States) - See all my reviews
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This review is from: Electron Paramagnetic Resonance: Elementary Theory and Practical Applications (Hardcover)
Electron paramagnetic resonance is a fairly complicated experimental technique, and the task of writing a textbook on this method is extremely challenging. This particular book is written by experienced scientists and covers all major modifications of EPR, as well as extensive bibliography. However, the presentation of the material could be much, much better. I found it very hard to follow the authors mostly because the systematics in presentation, from full explanation of simple things to more complicated ones, is lacking almost completely. Sometimes I even had a strange feeling that subsections of the book were written independently and were just put next to each other in the final manuscript, so different is their writing style, and so weakly they are related to each other. Unfortunately, there are not so many books on EPR published recently which are available at bookstores, so the readers do not have a lot of choice...
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Inside This Book (learn more)
First Sentence:
The science of electron paramagnetic resonance (EPR) spectroscopy is very similar in concept to the more familiar nuclear magnetic resonance (NMR) technique. Read the first page
Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
hyperfine matrices, hyperfine matrix, proton hyperfine splittings, benzene anion, lineshape effects, naphthalene anion, hyperfine effects, secondary quantum number, microwave saturation, constant microwave frequency, interacting nucleus, coupled representation, isotropic hyperfine interaction, hyperfine anisotropy, spin hamiltonian, spectral extent, hyperfine term, magnetic species, hyperfine splitting constants, spin population, inorganic radicals, transition ions, quadrupole parameter, uniaxial symmetry, equivalent nuclei
Key Phrases - Capitalized Phrases (CAPs): (learn more)
New York, Oxford University Press, Van Nostrand Reinhold, Cambridge University Press, Solid State Physics, Englewood Cliffs, Molecular Biophysics, Nuovo Cimento
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