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Equation of State of Uranium Dioxide: Data Collection
 
 
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Equation of State of Uranium Dioxide: Data Collection [Hardcover]

C. Ronchi (Author), I.L. Iosilevski (Author), E.S. Yakub (Author)

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Book Description

3540221220 978-3540221227 August 26, 2004 1

The monograph deals with the thermodynamic properties of fluid uranium dioxide, one of the most investigated materials of the last century, up to its critical point. It presents an exhaustive theoretical introduction to "quasi-chemical" models of liquids, as well as their behaviour under non-congruent vaporisation conditions. Particular emphasis is given to the properties of pure Coulombic systems and to the pseudoparticle approach, which enables the partition function to be expressed in a simple, but physically rigorous formulation. The construction of the equation of state of stoichiometric and non-stoichiometric uranium dioxide is described in distinct steps, from a critical assessment of the theoretical fundamentals to a thorough review of the pertinent thermochemical and thermophysical data. Calculations of the thermodynamic properties of UO2+x are performed for temperatures up to 10,000 K both for the condensed and gas phase. More than one hundred tables are collected in the Appendix, containing all relevant thermodynamic data.


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The monograph deals with the thermodynamic properties of fluid uranium dioxide, one of the most investigated materials of the last century, up to its critical point. It presents an exhaustive theoretical introduction to "quasi-chemical" models of liquids, as well as their behaviour under non-congruent vaporisation conditions. Particular emphasis is given to the properties of pure Coulombic systems and to the pseudoparticle approach, which enables the partition function to be expressed in a simple, but physically rigorous formulation. The construction of the equation of state of stoichiometric and non-stoichiometric uranium dioxide is described in distinct steps, from a critical assessment of the theoretical fundamentals to a thorough review of the pertinent thermochemical and thermophysical data. Calculations of the thermodynamic properties of UO2+x are performed for temperatures up to 11,000 K both for the condensed and gas phase. More than one hundred tables are collected in the Appendix containing all relevant thermodynamic data.


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Inside This Book (learn more)
First Sentence:
For more than fifty years, uranium dioxide was world-wide used as the main fuel for two generations of nuclear power plants. Read the first page
Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
liquid uranium dioxide, primitive ionic model, vapour coexisting, congruent vaporisation, vaporisation conditions, pure ionic model, radii dispersion, total vapour pressure, oxygen chemical potential, coexisting vapour, boiling curve, oxygen potential, ionisation equilibrium, saturated vapour, true critical point, charged hard spheres, partial vapour pressure, dissociation degree, ionic models, intrinsic volumes, coexisting phases, equilibrium composition, maximal temperature, ionisation potentials, ionic liquids
Key Phrases - Capitalized Phrases (CAPs): (learn more)
Mean Spherical Approximation
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