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High Resolution NMR in the Solid State: Fundamentals of CP/MAS
 
 
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High Resolution NMR in the Solid State: Fundamentals of CP/MAS [Hardcover]

E. O. Stejskal (Author), J. D. Memory (Author)

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Book Description

August 25, 1994 0195073800 978-0195073805 1
This text was developed from a course for physical chemistry and chemical physics students using cross-polarization (CP) magic angle spinning (MAS) NMR in their laboratory assignments. The book provides students with the details of the CP/MAS experiment as it is used to obtain rare-spin, high-resolution NMR spectra. The design of the CP/MAS experiments and the interpretation of spectra and relaxation measurements require an understanding of the interplay of several fundamental physical interactions not normally encountered in solution NMR. The student can observe the way interacting spin systems behave in the solid state, and have a quantum mechanically rigorous understanding of solid-state spin phenomena. The text will have the added benefit of serving as a self-study resource for students seeking to learn the underlying principles of laboratory experiments using the technique. The history of NMR is also treated, and the instrumentation of the spectrometer and probe are discussed.

Editorial Reviews

Review

"A fascinating introduction to the subject ... highly recommend it to those wishing to make the jump from solution NMR. " -- NMR Newsletter

About the Author

E. O. Stejskal is at North Carolina State University.

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Inside This Book (learn more)
First Sentence:
In this chapter, we will discuss the general principles of nuclear magnetic resonance (NMR), beginning with fundamental definitions and an introduction to the basic experiment, then writing down the Bloch Equations to describe the macroscopic nuclear magnetization and solving them for both continuous wave and pulse conditions. Read the first page
Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
abundant spin system, magic angle hopping, crossed diodes, spin temperature, abundant spins, sample coil, rotor period, spinning sidebands, nuclear magnetization, density matrix theory, dipolar broadening, sample spinning, isotropic line, spin magnetization, chemical shielding, thermal equilibrium value, nuclear magnetic relaxation, strong external magnetic field, rotating frame, spin echoes, chemical shift anisotropy, random rotation, dipolar coupling, polarization transfer
Key Phrases - Capitalized Phrases (CAPs): (learn more)
American Institute of Physics, Academic Press, New York, Rotating Solids, Zeeman Hamiltonian, Clarendon Press, Lowe-Tarr Tee, Concepts Magn, John Wiley, Nuclear Double Resonance, Oxford University Press, Relaxation Effects, Solid Glassy Polymers
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