From the Publisher
Imparts the similarities and differences between ratified and condensed matter, classical and quantum systems as well as real and ideal gases. Presents the quasi-thermodynamic theory of gas-liquid interface and its application for density profile calculation within the van der Waals theory of surface tension. Uses inductive logic to lead readers from observation and facts to personal interpretation and from specific conclusions to general ones.
From the Inside Flap
An updated and expanded translation of the highly popular Russian textbook, Introduction to Thermodynamics and Kinetic Theory of Matter examines equilibrium and kinetic properties of matter-gas, liquid, and solid-using the general principles of thermodynamics and kinetic theory. Readable and accessible throughout, this book provides both thermodynamic and statistical points of view, covering thermodynamic potentials, such as entropy and free energy, whenever relevant. The book takes a fresh approach to its subject matter, focusing equally on condensed matter and gases. It compares rarefied and condensed matter, classical and quantum systems, and real and ideal gases. Central to the book are intermolecular interactions, and the process by which they lead matter into a change of state. The author discusses the solid, crystalline phase, showing how it can be manipulated by lattice vibration as well as by thermal pressure. In addition, this is the only book in which the quasithermodynamic theory of gas/liquid interface is used for density profile calculation within the van der Waals theory of surface tension. Another major theme investigated here is the irreversible transfer properties of matter, such as diffusion and viscosity, heat and electric conductivity. The book presents the hypothesis of "local equilibrium," which facilitates the calculation of the fluxes of matter, heat, or charge-comparing them and predicting the resultant density and temperature dependencies of transport coefficients. Examples from situations when local equilibrium is absent are also included. Finally, the book covers all reversible processes subject to the principles of thermodynamics. This is especially useful in experimental applications-optimizing the work of heat engines and pumps; providing methods for the condensation of gases into liquids; and explaining various phenomena such as phase equilibrium and transitions, surface tension, and thermal radiation. Addressing a broad audience, and using inductive logic and many illustrations, Introduction to Thermodynamics and Kinetic Theory of Matter leads the reader from basic phenomena to advanced models, and provides from the outset opportunities for experimental work in related fields of physics and physical chemistry.