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Ionic Equilibrium: Solubility and pH Calculations [Hardcover]

James N. Butler (Author)
5.0 out of 5 stars  See all reviews (2 customer reviews)

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Book Description

March 30, 1998 0471585262 978-0471585268
A celebrated classic in the field updated and expanded to include the latest computerized calculation techniques

In 1964, James N. Butler published a book in which he presented some simple graphical methods of performing acid-base, solubility, and complex formation equilibrium calculations. Today, both the book and these methods have become standard for generations of students and professionals in fields ranging from environmental science to analytical chemistry. Named a "Citation Classic" by the Science Citation Index in 1990, the book, Ionic Equilibrium, continues to be one of the most widely used texts on the subject. So why tamper with near-perfection by attempting a revision of that classic? The reason is simple-- the recent rapid development and wide availability of personal computers.

In the revised Ionic Equilibrium, Dr. Butler updates his 1964 work by abandoning the slide rule and graph paper for the PC spreadsheet. He also expands the original coverage with extensive material on basic principles and recent research.

The first part of Ionic Equilibrium is devoted to the fundamentals of acid-base, solubility, and complex formation equilibria. In the second part, the author discusses oxidation-reduction equilibria, develops the principles of carbon dioxide equilibria, presents case studies demonstrating the ways in which carbon dioxide equilibria are used in physiology and oceanography, and explores the possibility of a pH scale for brines. The concluding chapter, written by David R. Cogley, gives examples of general computer programs that are capable of performing equilibrium calculations on systems of many components.

Replete with real-world examples, details of important calculations, and practical problems, Ionic Equilibrium is an ideal course text for students of environmental chemistry, engineering, or health; analytical chemistry; oceanography; geochemistry; biochemistry; physical chemistry; and clinical chemistry. It is also a valuable working resource for professionals in those fields as well as industrial chemists involved with solution chemistry.

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Editorial Reviews

Review

"This is by far the best textbook on chemical equilibrium I know. It is an absolute must for everybody using electrolyte solutions in his research..."(Jnl of Solid State Electrochemistry, Vol 5, 2001)

From the Publisher

Ionic equilibrium is the chemistry associated with salts, acids, and bases. The main application lies in environment science, especially the field of water chemistry. An example of ionic equilibrium studies in would be the examination of environmental damages caused to the Alaskan waters by the Exxon Valdez oil spill (a project to which Dr. Butler has close ties). In 1964, Dr. Butler developed a simple yet powerful method of performing equilibrium calculations in the classic Addison-Wesley book, Solubility and pH Calculations. At that time, chemists utilized slide rules and graph paper to figure and plot these equations. This updated version is expanded to include new advances in the field and to incorporate the use of the personal computer into this branch of chemistry.

Product Details

  • Hardcover: 559 pages
  • Publisher: Wiley-Interscience (March 30, 1998)
  • Language: English
  • ISBN-10: 0471585262
  • ISBN-13: 978-0471585268
  • Product Dimensions: 9.6 x 6.4 x 1.3 inches
  • Shipping Weight: 2 pounds (View shipping rates and policies)
  • Average Customer Review: 5.0 out of 5 stars  See all reviews (2 customer reviews)
  • Amazon Best Sellers Rank: #343,307 in Books (See Top 100 in Books)

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2 of 2 people found the following review helpful:
5.0 out of 5 stars Aqueous Electrolytes Thermodynamics, December 29, 2010
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This review is from: Ionic Equilibrium: Solubility and pH Calculations (Hardcover)
This is an outstanding discussion of aqueous Ionic Equilibrium. This book is the third in a series written by James Butler. Earlier books are: Ionic Equilibrium A Mathematical Approach Addison Wesley 1964 ISBN 0-201-00730-4 547 pages and Solubility and pH Calculations Addison Wesley 1964 ISBN 0-201-00733-9 104 pages. The second book is a very good introduction to the chemistry of aqueous electrolyte solutions with less emphasis on the mathematics. Used copies are available from Amazon and Ebay.

I suggest that you first read and study the Solubility and pH Calculations book. This will give you a view of the forest. Then read and study the Ionic Equilibrium book, this will give you a view of the trees.

I used the Ionic Equilibrium book for a class I taught to Chemical Engineers at Rowan University a couple years ago.

I also recomend the new book, An Introduction to Aqueous Electrolyte Solutions by Margaret Bobson Wright, Wiley 2007 ISBN 978-0-470-84293-5 574 pages. This is a very good description of the chemistry. It has very good worked examples but NO references.

The chemical description of pH or equilibrium result in a set of non-linear equations. The above books discuss methods to solve these equation based on approximations and sequentical calculations. If you are serious about solving many large equation sets you need to buy equation solving software. Suggested software;
* TK Solver from Universal Technical Systems @ [...], ( a general purpose non-linear equation solver)
* [...] ( this is a big time powerful commercial system with large database of thermodynamic properties)
* PolyMath by Professor Cutlip at University of Connecticut sorry that I don't have a better ref but you can look this up in Amazon or Google.
*
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0 of 3 people found the following review helpful:
5.0 out of 5 stars Very good sealer, May 28, 2009
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This review is from: Ionic Equilibrium: Solubility and pH Calculations (Hardcover)
I'm from Rio de Janeiro, Brazil, And I bought this book as an used book at 04/27/2009, the book was delivered 3 weeks after and it looks like a brand new book, awesome quality. I recomend this sealer
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Inside This Book (learn more)
First Sentence:
What You Need to Know Equilibrium When Is a System at Equilibrium? Read the first page
Key Phrases - Capitalized Phrases (CAPs): (learn more)
New York, Electrolyte Solutions, Critical Stability Constants, Geological Survey, Plenum Press, Aquatic Chemistry, American Chemical Society, Deep-Sea Res, Symposium Series, National Bureau of Standards, Boca Raton, Sandia National Laboratories, Environmental Protection Agency, Eriochrome Black, Faraday Soc, Ion Association, Name Formula, Apple Power Macintosh, John Wiley, Pure Appl, Bureau Standards, Donald Langmuir, Indian Ocean, Metal Ammine Formation, North Holland
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