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Ligand Field Theory and Its Applications (Special Topics in Inorganic Chemistry) [Hardcover]

Brian N. Figgis (Author), Michael A. Hitchman (Author)

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Book Description

December 28, 1999 0471317764 978-0471317760 1
A complete, up-to-date treatment of ligand field theory and its applications Ligand Field Theory and Its Applications presents an up-to-date account of ligand field theory, the model currently used to describe the metal-ligand interactions in transition metal compounds, and the way it is used to interpret the physical properties of the complexes. It examines the traditional electrostatic crystal field model, still widely used by physicists, as well as covalent approaches such as the angular overlap model, which interprets the metal ligand interactions using parameters relating directly to chemical behavior.

Written by internationally recognized experts in the field, this book provides a comparison between ligand field theory and more sophisticated treatments as well as an account of the methods used to calculate the energy levels in compounds of the transition metals. It also covers physical properties such as stereochemistry, light absorption, and magnetic behavior. An emphasis on the interpretation of experimental results broadens the book's field of interest beyond transition metal chemistry into the many other areas where these metal ions play an important role.

As clear and accessible as Brian Figgis's 1966 classic Introduction to Ligand Fields, this new book provides inorganic and bioinorganic chemists as well as physical chemists, chemical physicists, and spectroscopists with a much-needed overview of the many significant changes that have taken place in ligand field theory over the past 30 years.

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Editorial Reviews

Review

"Figgis and Hitchman have done an excellent job of bringing an old classic up-to-date and making it very usable for upper-division undergraduates...and for graduate students and faculty." (Choice, Vol. 38, No. 7, March 2001)

"...[the authors] explain how it [Ligand field theory] is used to interpret the physical properties of the complexes."and faculty." (SciTech Book News, March 2001)

"...serves its purpose with clarity." (Aslib Book Guide, July 2000)

"...a thoroughly re-worked version of an excellent book...excellent as an advanced undergraduate or introductory graduate level course in inorganic chemistry and as a resource for graduate students..." (Journal of Molecular Graphics Modelling, Vol. 19, No. 6, 2001)

"...a well balanced, practical, and readable monograph on an attractive area of inorganic chemistry." (Angewandte Chemie International Edition, Vol. 40 No. 10)

"...thoroughly recommended...an excellent addition to the literature..." (Journal of Chemical Education, Vol. 79, No. 9, September 2002)

From the Back Cover

A complete, up-to-date treatment of ligand field theory and its applications Ligand Field Theory and Its Applications presents an up-to-date account of ligand field theory, the model currently used to describe the metal-ligand interactions in transition metal compounds, and the way it is used to interpret the physical properties of the complexes. It examines the traditional electrostatic crystal field model, still widely used by physicists, as well as covalent approaches such as the angular overlap model, which interprets the metal ligand interactions using parameters relating directly to chemical behavior.

Written by internationally recognized experts in the field, this book provides a comparison between ligand field theory and more sophisticated treatments as well as an account of the methods used to calculate the energy levels in compounds of the transition metals. It also covers physical properties such as stereochemistry, light absorption, and magnetic behavior. An emphasis on the interpretation of experimental results broadens the book's field of interest beyond transition metal chemistry into the many other areas where these metal ions play an important role.

As clear and accessible as Brian Figgis's 1966 classic Introduction to Ligand Fields, this new book provides inorganic and bioinorganic chemists as well as physical chemists, chemical physicists, and spectroscopists with a much-needed overview of the many significant changes that have taken place in ligand field theory over the past 30 years.

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Inside This Book (learn more)
First Sentence:
hollows in the contour map, and the minor regions of unpaired spin density associated with the four fluoride ions indicate some small degree of covalency. It is quite easy to see that the members of the t set are equally affected by the presence of the ligand atoms because they are of identical shape and are symmetrically disposed relative to the ligands. Read the first page
Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
corresponding octahedral complex, angular overlap matrix, octahedral crystal field potential, cubic ligand field, ligand field potential, transition series ions, free ion terms, electrostatic crystal field theory, superhyperfine parameters, hexaaqua complexes, electrostatic crystal field model, ligand field terms, ligand field parameters, tetrahedral stereochemistry, nephelauxetic ratio, octahedral stereochemistry, crystal field approach, single electron wavefunctions, ligand field effects, coordination cluster, orbital set, actinide complexes, octahedral ligand field, ligand orbitals, interelectron repulsion
Key Phrases - Capitalized Phrases (CAPs): (learn more)
New York, Electrons Figure, Intermediate Strong-field Strong-field, Academic Press, Ion Compound, Marcel Dekker, Plenum Press, Quantum Chemistry, Transition Metal Chemistry
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