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Molecular Thermodynamics of Electrolyte Solutions [Paperback]

Lloyd L. Lee (Author)
4.0 out of 5 stars  See all reviews (1 customer review)

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Book Description

9812814191 978-9812814197 July 8, 2008 Pap/Cdr
The introductory textbook provides an update on electrolyte thermodynamics with a molecular perspective. It is eminently suited as an introduction to the solution thermodynamics of ionic mixtures at the undergraduate and graduate level. It is also invaluable for the understanding and design in the engineering of natural gas treating and adsorption refrigeration with electrolytes.

Contents: Solution Thermodynamics of Electrolyte Solutions; Basic Electrostatics; The Debye Hückel Theory; Pitzer s Formulation for Electrolytes; The Statistical Mechanics of Electrolytes; Ions as Charged Hard Spheres: The Mean Spherical Approach; The McMillan-Mayer and Lewis-Randall Scales; Multi-Solvent Electrolyte Solutions: Setchenov s Salting-Out Principle; Ionic Distributions: An Integral Equation Approach; The Electric Double Layers; Application: Adsorption Refrigeration with Electrolytes; Application: Amine Solutions in Acid Gas Treating.


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Product Details

  • Paperback: 264 pages
  • Publisher: World Scientific Publishing Company; Pap/Cdr edition (July 8, 2008)
  • Language: English
  • ISBN-10: 9812814191
  • ISBN-13: 978-9812814197
  • Product Dimensions: 8.9 x 5.9 x 0.6 inches
  • Shipping Weight: 14.9 ounces (View shipping rates and policies)
  • Average Customer Review: 4.0 out of 5 stars  See all reviews (1 customer review)
  • Amazon Best Sellers Rank: #2,714,006 in Books (See Top 100 in Books)

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4.0 out of 5 stars Good read, December 10, 2009
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The book provides a nice introduction to thermodynamics of electrolyte solutions. First 5 chapters should be readily accessible to undergraduate students. The prose is a bit unattractive and has many rough edges. A part of the book reads more like lecture notes than a carefully crafted exposition. A phrase such as "the chemical potential for the forward reaction," which is inappropriate since the chemical potential is a state variable, adds to the discomfort every now and then. Nevertheless, overall presentation is very clear and highly accessible. The book places more emphasis on practical calculations than on an in-depth look into the foundation of electrolyte thermodynamics. I would recommend the book for anyone who is looking for an introductory account of this important field.

My big disappointment was in typesetting. For example, notation for a vector in the main text differs from that in the equation. There are many large white spaces, especially around large figures. For a book of only 251 pages and yet costing as much as $83.00, I should expect a more professional quality typesetting from the publisher.

The book comes with a CD-ROM containing executables for things like activity coefficient calculation under mean-spherical-approximation. No source code is included. CD-ROM is in UDF format and may not be accessible for some CD-ROM/DVD drives. This was the case with my laptop with an external DVD drive even after installing the UDF reader which came with the book's CD-ROM. It worked flawlessly on my older laptop with an internal drive.
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Inside This Book (learn more)
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Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
spherical approach, integral equation approach, mean activity coefficient, salt species, bridge function, absorption refrigeration, osmotic coefficient, solvent activity, slipping plane, vapor pressure curves, absorption cycle, electric double layers, amine solutions
Key Phrases - Capitalized Phrases (CAPs): (learn more)
Molecular Thermodynamics of Electrolyte Solutions, Ionic Distributions, The Electric Double Layers, Lewis-Randall Scales, Multi-Solvent Electrolyte Solutions, The Mean Spherical Approach, The Statistical Mechanics of Electrolytes, Monte Carlo, Fourrier Transformed, Use Pitzer, Acid Gas Treating
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