Paramagnetic transition metal ions provide the opportunity for application of a wide variety of spectroscopic techniques. Although spectroscopic techniques are not as well known as conventional nuclear magnetic resonance (NMR), they provide detailed information centered on the active site itself. This book describes the application of paramagnetic resonance techniques to a number of important systems in metallobiochemistry. Simultaneously, this volume provides information on novel experimantal methods and theoretical approaches to understanding the structure and function of metalloenzymes and other metallobiomolecules. The specific techniques described include electron paramagnetic resonance (EPR) spectroscopy, and its derivative techniques, electron nuclear double resonance (ENDOR) and electron spin echo envelope modulation (ESEEM). These latter two techniques directly probe the nuclear environment of the paramagnetic active site, without interference from magnetically active nuclei that are not involved in the active site. Magnetic circular dichroism (MCD), which links magnetic resonance and oprical spectrospoy, is also described. The application of MCD to problems in metallobiochemistry is growing rapidly, yet uhere are few sources that clearly describe this complex technique. This volume provides several approaches involving MCD. Finally, this book also includes a wide variety of biological systems including heme proteins, iron-sulfur proteins, molybdopterins, manganese proteins, and copper proteins, as well as non-protein biological molecules, such as ribozymes.
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First Sentence:
The historical background and goals of this ACS Symposium Series volume is given. Read the first page Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
cluster binding loop, ferric pair, subspin pairs, heme methyl resonances, ferriheme proteins, hfi parameters, mixed valence pair, dipicolinate complexes, electron spin delocalization, metal binding loop, electronic isomers, blue copper sites, zfs interaction, pseudocontact shifts, paramagnetic proteins, intradiol dioxygenases, sulfido ligand, dipolar contacts, enzyme strand, hyperfine tensor, hyperfine shifts, shift increments, conformational selection, electron spin density, bend magnets Key Phrases - Capitalized Phrases (CAPs): (learn more)
American Chemical Society, New York, Chem Soc, Magn Reson, Academic Press, Inorg Chem, Ortiz de Montellano, University of California, Brian Hoffman, John Wiley, Plenum Press, Northwestern University, Chem Phys, Mansfield Matera, Oxford University Press, Phys Chem, Protein Chem, San Diego, The Netherlands, Biol Chem, Inorganic Division, New Jersey, Stanford University, Symposium Series, The Porphyrin Handbook New!
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Front Cover | Table of Contents | First Pages | Index | Back Cover | Surprise Me!
The historical background and goals of this ACS Symposium Series volume is given. Read the first page Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
cluster binding loop, ferric pair, subspin pairs, heme methyl resonances, ferriheme proteins, hfi parameters, mixed valence pair, dipicolinate complexes, electron spin delocalization, metal binding loop, electronic isomers, blue copper sites, zfs interaction, pseudocontact shifts, paramagnetic proteins, intradiol dioxygenases, sulfido ligand, dipolar contacts, enzyme strand, hyperfine tensor, hyperfine shifts, shift increments, conformational selection, electron spin density, bend magnets Key Phrases - Capitalized Phrases (CAPs): (learn more)
American Chemical Society, New York, Chem Soc, Magn Reson, Academic Press, Inorg Chem, Ortiz de Montellano, University of California, Brian Hoffman, John Wiley, Plenum Press, Northwestern University, Chem Phys, Mansfield Matera, Oxford University Press, Phys Chem, Protein Chem, San Diego, The Netherlands, Biol Chem, Inorganic Division, New Jersey, Stanford University, Symposium Series, The Porphyrin Handbook New!
Books on Related Topics | Concordance | Text Stats Browse Sample Pages:
Front Cover | Table of Contents | First Pages | Index | Back Cover | Surprise Me!
Citations (learn more)
This book cites 35
books:
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cites this book:
- Biological Magnetic Resonance by Lawrence Berliner on page 11, page 53, and page 149
- The Porphyrin Handbook, Volumes 1-10 by Karl Kadish on page 257, and page 325
- Iron-Sulfur Proteins / Perovskites (Structure and Bonding) by I. Bertini on page 272, and page 284
- Principles of Pulse Electron Paramagnetic Resonance by Arthur Schweiger on page 10, and page 80
- Electron Paramagnetic Resonance of Transition Ions by A. Abragam on page 10, and page 338
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- Handbook of Applied Solid State Spectroscopy by D.R. Vij on page 193
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