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Purification of Laboratory Chemicals [Paperback]

D D PERRIN (Author), W.L.F. Armarego (Author)
4.0 out of 5 stars  See all reviews (5 customer reviews)


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Paperback, November 26, 1997 --  
There is a newer edition of this item:
Purification of Laboratory Chemicals, Sixth Edition Purification of Laboratory Chemicals, Sixth Edition 4.0 out of 5 stars (5)
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Book Description

0750637617 978-0750637619 November 26, 1997 4th
The purpose of this book is to help chemists, biochemists and other scientists purify the chemical reagents which they use in their work. Despite the fact that commercially available chemicals are often of a very high quality, and quite satisfactory for some applications within science and technology, it is becoming almost as important to know what impurities are present and make allowance for them as to remove them completely. This book will show you how.

Chapter 1 has been reorganised and updated, and most of it is in smaller print in order not to increase the size of the book. Chapters 2 and 5 have been similarly altered and combined into one chapter, Chapter 2, again in order to save pages. 800 and 350 entries have been added to Chapter 3 (25% increase) and Chapter 4 (44% increase) respectively, and 400 entries (310% increase) were added to Chapter 5 (Chapter 6 in the third edition) making a total of 5700 entries, all resulting in an increase from 319 to 529 pages, i.e. ca 35%. This considerably expanded and revised fourth edition includes much new material dealing with modern reagents for natural products chemistry, protein biochemistry and molecular biology. It also includes many individual compounds not previously covered, and more information is given for most entries, including melting and boiling points, molecular weights, refractive indexes, densities and CAS registry numbers, as well as likely contaminants and storage conditions in appropriate cases.




Editorial Reviews

Review

Professor Perrin and Armarego have done a commendable job in updating what has become a classic refernce. Visually this edition has significantly improved from the previous edition. Enlarging the pages and printing the book with a laser printer makes it more aesthetically appealing. More importantly, the amount of information has substantially increased. Additional chemicals have been added to the book and almost every entry now has the Chemical Abstracts registry number and molecular weight. Liquids have freezing point, boiling point, refractive index, and density information. Solids include a melting point and an occasional boiling point. Chiral molecules list a specific rotation. Unique hazards are also listed for some chemicals.
Journal of the American Chemical Society Vol 112, No 12,
--This text refers to an out of print or unavailable edition of this title.

Book Description

Purification of Laboratory Chemicals is vital for minimizing potentially dangerous reactions, as well as maximizing the integrity of chemicals used to process a product that must adhere to rigorous scientific standards. --This text refers to an out of print or unavailable edition of this title.

Product Details

  • Paperback: 544 pages
  • Publisher: Butterworth-Heinemann; 4th edition (November 26, 1997)
  • Language: English
  • ISBN-10: 0750637617
  • ISBN-13: 978-0750637619
  • Product Dimensions: 8.4 x 5.8 x 0.7 inches
  • Shipping Weight: 12.6 ounces
  • Average Customer Review: 4.0 out of 5 stars  See all reviews (5 customer reviews)
  • Amazon Best Sellers Rank: #3,674,293 in Books (See Top 100 in Books)

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19 of 20 people found the following review helpful:
4.0 out of 5 stars Great for the Organic Chemist, December 31, 1998
This review is from: Purification of Laboratory Chemicals (Paperback)
Like Carey & Sundberg, Jerry March, the Aldrich catalog, and the Merck Index, (etc.), this book should be a benchmate for the Organic Chemist. It is very good when one requires the purification of reagents, or the drying/purification of solvents. The protocols for purification are usually pretreatment followed by distillation or recrystallization, and can be carried out to give anywhere from moderately pure material, to giving the pure, pure substance.

Excellent for the research organic chemistry graduate student or the pharmaceutical industrial research chemist who likes to start with the purest materials, so as to leave only the investigative variables open to question.

However, in industry, although FedEx-ing new and pure reagents (and disposal of the old questionable ones!) is the easiest and encouraged method for research, it is often found that purification is totally appropriate--in these instances, Purification of Laboratory Chemicals (D.D. Perrin & W.L.F. Armarego) is highly recommended.

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11 of 11 people found the following review helpful:
4.0 out of 5 stars An Absolute Essential for Chemists!, November 17, 2000
This review is from: Purification of Laboratory Chemicals (Paperback)
As a chemist, I am often in need of techniques for purification of various chemicals. Often time is a constraint and the "best" technique may be too time consuming, if one even knows what it is. This text offers several alternatives to the purificatin of most common compounds (especially solvents), including the best way to make the compound pure as well as other known techniques. One can then choose, based on the reaction one is doing whether one needs to use the best techniques or the fastest technique to get mostly pure material or somewhere inbetween. Unfortunately, often the text does not list the actual percent purity that each technique can yield (though it is often easy enough to guess which methodology will yield the best results.) An invaluable resource for any chemist, but especially for graduate students.
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5 of 6 people found the following review helpful:
5.0 out of 5 stars Great for the "Synthetic" Chemist, June 5, 2000
By 
Craig MACKINNON (Thunder Bay, Ontario Canada) - See all my reviews
This review is from: Purification of Laboratory Chemicals (Paperback)
This is an indispensible resource for any synthetic chemist, either organic or inorganic (not sure about the biochemical section). This book has concise, informative entries on the purification of a vast number of common solvents and reagents. I don't know how any chemist can survive without having this on his/her bookshelf!
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Inside This Book (learn more)
First Sentence:
Purity is a matter of degree. Read the first page
Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
fractional distn, distd water, vacuum distd, white ppte, pet ether, washed with ethyl ether, ether soln, benzene soln, saturated aqueous soln, distil under vacuum, wash with aqueous, adding ethyl ether, vac desiccator, bisulphite addition compound, alumina before use, olefinic impurities, distillate solidifies, glass helices, been recrystallised, soln containing, alkaline soln, fractional freezing, saturated soln, likely impurities, distil the residue
Key Phrases - Capitalized Phrases (CAPs): (learn more)
Org Synth Coll Vol, Acta Chem Scand, Handbook of Preparative Inorganic Chemistry, Inorg Synth, Bull Soc Chim France, Biochim Biophys Acta, Res Nat Bur Stand, Academic Press, Bull Chem Soc Japan, Rec Trav Chim Pays Bas, Chem Pharm Bull Japan, Arch Biochem Biophys, Pharm Soc Japan, New York, Perkin Trans, The Enzymes, Biochem Biophys Acta, Dekker Inc, Engl Edn, Inorg Chem, Pergamon Press, Acta Cryst, Anal Chim Acta, Appl Chem, Chem Abs
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