Molecular ruthenium catalysts, during the last decade, have provided new indispensable synthetic methods that cannot be promoted by other catalysts, and they now constitute an emerging field for the selective preparation of fine chemicals. The major reaction types for carbon-carbon and carbon-heteroatom bond formation, most of them with atom economy, are comprehensively discussed by leading experts. The authors highlight the most important discoveries in ruthenium catalysis and propose activation processes, some of them being still controversial. They illustrate the innovation and usefulness in organic synthesis of specific reactions including carbocyclization, cyclopropanation, olefin metathesis, carbonylation, oxidation, transformation of silicon containing substrates, and show novel reactions operating via vinylidene intermediates, radical processes, inert bonds activation as well as catalysis in water. Therefore, the reader will receive a balanced view of this rapidly developing field.
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ruthenium vinylidene complexes, bond forming cyclizations, silylative coupling, unsaturated organosilicon compounds, enyne cycloisomerization, vinylidene species, ruthenium vinylidenes, ruthenium catalysis, enyne metathesis, vinylidene intermediate, efficient catalyst precursors, allenylidene complexes, dehydrogenative silylation, carbonylation reactions, ruthenium center, ruthenium catalysts, alkene metathesis, ruthenium carbene complexes, ruthenium complexes, ruthenium species, terminal alkynes, silicon derivatives, internal alkynes, bond formation reactions, olefin coordination Key Phrases - Capitalized Phrases (CAPs): (learn more)
Chem Commun, Tetrahedron Lett, Org Chem, Organomet Chem, Org Lett, Angew Chem Int Ed Engl, Chem Rev, Chem Lett, Mol Catal, New York, Adv Synth Catal, Bull Chem Soc Jpn, Acc Chem Res, Mitsudo T-a, Chem Eur, Springer-Verlag Berlin Heidelberg, Chem Soc Perkin Trans, Concluding Remarks, Tetrahedron Asymmetry, Chem Soc Dalton Trans, Reactions Involving Addition of Water, Active Catalytic Intermediates, Addition of Terminal Alkynes, Carbonyl Functionality, Department of Applied Chemistry New!
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ruthenium vinylidene complexes, bond forming cyclizations, silylative coupling, unsaturated organosilicon compounds, enyne cycloisomerization, vinylidene species, ruthenium vinylidenes, ruthenium catalysis, enyne metathesis, vinylidene intermediate, efficient catalyst precursors, allenylidene complexes, dehydrogenative silylation, carbonylation reactions, ruthenium center, ruthenium catalysts, alkene metathesis, ruthenium carbene complexes, ruthenium complexes, ruthenium species, terminal alkynes, silicon derivatives, internal alkynes, bond formation reactions, olefin coordination Key Phrases - Capitalized Phrases (CAPs): (learn more)
Chem Commun, Tetrahedron Lett, Org Chem, Organomet Chem, Org Lett, Angew Chem Int Ed Engl, Chem Rev, Chem Lett, Mol Catal, New York, Adv Synth Catal, Bull Chem Soc Jpn, Acc Chem Res, Mitsudo T-a, Chem Eur, Springer-Verlag Berlin Heidelberg, Chem Soc Perkin Trans, Concluding Remarks, Tetrahedron Asymmetry, Chem Soc Dalton Trans, Reactions Involving Addition of Water, Active Catalytic Intermediates, Addition of Terminal Alkynes, Carbonyl Functionality, Department of Applied Chemistry New!
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Front Cover | Table of Contents | First Pages | Index | Back Cover | Surprise Me!
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11
books
cite this book:
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- Metal Carbenes in Organic Synthesis (Topics in Organometallic Chemistry) by Karl Heinz Dötz in Front Matter
- Surface and Interfacial Organometallic Chemistry and Catalysis (Topics in Organometallic Chemistry) by C. Copéret in Front Matter
- Theoretical Aspects of Transition Metal Catalysis (Topics in Organometallic Chemistry) by Gernot Frenking in Front Matter
- Palladium in Organic Synthesis (Topics in Organometallic Chemistry) by Jiro Tsuji in Front Matter
- Transition Metal Arene Pi-complexes In Organic Synthesis And Catalysis (Topics in Organometallic Chemistry) by Peter E. Kündig in Front Matter
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