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Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations (Advances in Polymer Science)
 
 
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Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations (Advances in Polymer Science) [Hardcover]

Kelly A. Davis (Author), Krzysztof Matyjaszewski (Author)

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Book Description

October 28, 2002 3540432442 978-3540432449 1
This review is focused on controlled/living radical polymerization methods for the preparation of various copolymers. A brief introduction to the subject of radical polymerization, and early attempts to control it, is followed by a detailed examination of the literautre on controlled/living radical copolymerizations from the mid-90's until 2001. The topics covered include statistical/gradient, block, graft, and star copolymers and the polymerization methods used to produce them. These copolymers were prepared using three major controlled radical methods (either nitroxide mediated polymerization, atom transfer radical polymerization or degenerative transfer) and a combination of polymerization techniques, including transformation chemistry or the simultaneous/dual living polymerizations, to achieve the desired chain architecture or topology. An evaluation of the current state of the field is also presented.

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Inside This Book (learn more)
Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
graft units, molecular weight shoulder, total monomer conversion, gradient copolymers, chain end functionality, new nitroxides, controlled radical polymerisation, increasing monomer conversion, predictable molecular weights, prepared block copolymers, blocking efficiency, degenerative transfer, experimental molecular weights, dormant species, multifunctional initiators, transformation chemistry, atom transfer radical polymerization, star polymers, hyperbranched polymers, initiating sites, halogen exchange, catalyst system, graft copolymers, chain extension, reactivity ratios
Key Phrases - Capitalized Phrases (CAPs): (learn more)
American Chemical Society, John Wiley, Block Catalyst Comments Investigator
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