Transition metal catalysis belongs to the most important chemical research areas because a ubiquitous number of chemical reactions are catalyzed by transition metal compounds. Many efforts are being made by industry and academia to find new and more efficient catalysts for chemical processes. Transition metals play a prominent role in catalytic research because they have been proven to show an enormous diversity in lowering the activation barrier for chemical reactions. For many years, the search for new catalysts was carried out by trial and error, which was costly and time consuming. The understanding of the mechanism of the catalytic process is often not very advanced because it is difficult to study the elementary steps of the catalysis with experimental techniques. The development of modern quantum chemical methods for calculating possible intermediates and transition states was a breakthrough in gaining an understanding of the reaction pathways of transition metal catalyzed reactions. This volume, organized into eight chapters written by leading scientists in the field, illustrates the progress made during the last decade. The reader will obtain a deep insight into the present state of quantum chemical research in transition metal catalysis.
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First Sentence:
Sigma-bond (including H-H, C-H and C-C) activation and formation are fundamental steps of many chemical transformations and have been subject of numerous review articles [1]. Read the first page Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
catalytic reaction course, enantioface conversion, tentative catalytic cycle, most feasible pathway, diperoxo complexes, moderate activation barrier, critical elementary steps, identical stereoisomers, second generation ligands, larger activation barrier, smaller activation barrier, diimine catalysts, quantum cluster, chelate phosphine, olefin pressure, ethylene insertion, heterocyclic spacer, thermodynamic population, saturated clusters, point charge field, stereochemical pathways, insertion barriers, allylic isomerization, polymer topology, boryl group Key Phrases - Capitalized Phrases (CAPs): (learn more)
Chem Rev, Phys Chem, Org Chem, Organomet Chem, American Chemical Society, New York, Angew Chem Int Ed Engl, Chem Phys, Chem Eur, Phys Rev, Acc Chem Res, Chem Commun, Tetrahedron Lett, Bull Chem Soc Jpn, Chem Soc Dalton Trans, Comput Chem, Springer-Verlag Berlin Heidelberg, Ethylene Polymerization Catalysed, Justus Liebigs Ann Chem, Product Fig, Academic Press, Tetrahedon Lett New!
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Front Cover | Table of Contents | First Pages | Index | Back Cover | Surprise Me!
Sigma-bond (including H-H, C-H and C-C) activation and formation are fundamental steps of many chemical transformations and have been subject of numerous review articles [1]. Read the first page Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
catalytic reaction course, enantioface conversion, tentative catalytic cycle, most feasible pathway, diperoxo complexes, moderate activation barrier, critical elementary steps, identical stereoisomers, second generation ligands, larger activation barrier, smaller activation barrier, diimine catalysts, quantum cluster, chelate phosphine, olefin pressure, ethylene insertion, heterocyclic spacer, thermodynamic population, saturated clusters, point charge field, stereochemical pathways, insertion barriers, allylic isomerization, polymer topology, boryl group Key Phrases - Capitalized Phrases (CAPs): (learn more)
Chem Rev, Phys Chem, Org Chem, Organomet Chem, American Chemical Society, New York, Angew Chem Int Ed Engl, Chem Phys, Chem Eur, Phys Rev, Acc Chem Res, Chem Commun, Tetrahedron Lett, Bull Chem Soc Jpn, Chem Soc Dalton Trans, Comput Chem, Springer-Verlag Berlin Heidelberg, Ethylene Polymerization Catalysed, Justus Liebigs Ann Chem, Product Fig, Academic Press, Tetrahedon Lett New!
Books on Related Topics | Concordance | Text Stats Browse Sample Pages:
Front Cover | Table of Contents | First Pages | Index | Back Cover | Surprise Me!
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- Organolithiums in Enantioselective Synthesis (Topics in Organometallic Chemistry) by David M. Hodgson in Front Matter
- Lanthanides: Chemistry and Use in Organic Synthesis (Topics in Organometallic Chemistry) (v. 2) by Shu Kobayashi in Front Matter
- New Aspects of Zirconium Containing Organic Compounds by Ilan Marek in Front Matter
- Metallocenes in Regio- and Stereoselective Synthesis (Topics in Organometallic Chemistry) (v. 8) by Tamotsu Takahashi in Front Matter
- Activation of Unreactive Bonds and Organic Synthesis (Topics in Organometallic Chemistry) by Shinji Murai in Front Matter
See all 9 books this book cites
- Metal Carbenes in Organic Synthesis (Topics in Organometallic Chemistry) by Karl Heinz Dötz in Front Matter
- Surface and Interfacial Organometallic Chemistry and Catalysis (Topics in Organometallic Chemistry) by C. Copéret in Front Matter
- Metallocenes in Regio- and Stereoselective Synthesis (Topics in Organometallic Chemistry) (v. 8) by Tamotsu Takahashi in Front Matter
- Precursor Chemistry of Advanced Materials: CVD, ALD and Nanoparticles (Topics in Organometallic Chemistry) by Roland A. Fischer in Front Matter
- Palladium in Organic Synthesis (Topics in Organometallic Chemistry) by Jiro Tsuji in Front Matter
See all 7 books citing this book
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