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Thermal Decomposition of Solids and Melts: New Thermochemical Approach to the Mechanism, Kinetics and Methodology (Hot Topics in Thermal Analysis and Calorimetry)
 
 
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Thermal Decomposition of Solids and Melts: New Thermochemical Approach to the Mechanism, Kinetics and Methodology (Hot Topics in Thermal Analysis and Calorimetry) [Hardcover]

Michael E. Brown (Adapter), Boris V. L'vov (Author)

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Book Description

October 3, 2007 1402056710 978-1402056710 1

This book covers the results of investigations into the mechanisms and kinetics of thermal decompositions of solid and liquid substances on the basis of thermochemical analyses of the processes. In the framework of the proposed ideas, the main features of these reactions are explained and many problems and unusual phenomena, which have accumulated in this field are interpreted. New methods of TA measurement and calculation have been developed, which permit the precision and accuracy of determination of kinetic parameters to be increased substantially. Reliable kinetic characteristics have been obtained and the decomposition mechanisms for several tens of substances have been interpreted. These include different classes of compounds: crystalline hydrates, oxides, hydroxides, nitrides, azides, nitrates, sulfates, carbonates and oxalates.


Editorial Reviews

Review

Aus den Rezensionen: "Das Buch ist eine Übersetzung aus dem Russischen mit Zusätzen und Verbesserungen. … Es beschäftigt sich mit der thermischen Zersetzung von Festkörpern und Schmelzen. … Ulgolkov beschreibt die instrumentellen Parameter thermodynamisch und erläutert sie an Beispielen. Das Buch schließt mit einem Index, Massekonstanten und Gasdruckdaten. Das Fachbuch wendet sich an Anwender der Thermischen Analysetechniken. Die thermodynamischen Effekte werden gut beschrieben …" (Robert Fuchs, in: Mitteilungsblatt der GDCh -Gesellschaft Deutscher Chemiker-, 2008, Issue 4, S. 12)

From the Back Cover

Thermal Decomposition of Solids and Melts describes the results of investigations into the mechanisms and kinetics involved in the thermal decomposition of solid and liquid substances via thermochemical analysis (TA). The main features of these thermal decomposition reactions are explained within and the observed anomalies are interpreted. New methods of TA measurement and calculation have been developed, which permit the precision and accuracy of determination of kinetic parameters to be increased substantially. Reliable kinetic characteristics have been obtained and the decomposition mechanisms for several substances have been interpreted. These include different classes of compounds: crystalline hydrates oxides hydroxides nitrides azides nitrates sulfates carbonates oxalates This book is intended for advanced undergraduates, researchers, and technologists working in the fields of engineering, metallurgy, chemistry, and material science.

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Inside This Book (learn more)
Key Phrases - Statistically Improbable Phrases (SIPs): (learn more)
dissociative vaporization, equimolar mode, oversaturated vapour, absolute decomposition rates, isobaric mode, condensation energy transfer, vaporization coefficients, primary gaseous products, vaporization equations, reactant melting, thermochemical approach, congruent vaporization, primary decomposition products, initial decomposition temperature, thermochemical analysis, thermochemical characteristics, thermal analyser, vaporization conditions, decomposition mode, germ nuclei, crystalline hydrates, decomposition conditions, molar enthalpy, foreign gases, thermochemical parameters
Key Phrases - Capitalized Phrases (CAPs): (learn more)
Thermochim Acta, Powder Vacuum, Phys Chem, Crystal Vacuum, Nauka Tekhnika, Spectrochim Acta, Therm Anal Cal, Chem Phys, Pellet Vacuum, Chem Soc, Anal Chem, Proc Roy Soc, Trans Faraday Soc, New York, Phys Rev, Decomposition Mechanism, Powder Air, Appl Chem, React Kinet Catal Lett, Primary Peqp Equilibrium Peq, Akad Nauk, Deduced Reaction, Effect of the Reactant Crystal Structure, Isothermal Arrhenius, Expt Theory
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